Atmospheric Chemistry and Chemical Mechanisms
نویسندگان
چکیده
INTRODUCTION........................................................................................................................... 1 OVERVIEW OF ATMOSPHERIC VOC OXIDATION ............................................................... 2 CURRENT STATE OF KNOWLEDGE ........................................................................................ 4 Inorganic Reactions............................................................................................................. 4 Organic Reactions ............................................................................................................... 5 Theoretical Estimates .......................................................................................................... 7 CHEMICAL MECHANISMS ........................................................................................................ 8 Summary of Chemical Mechanisms Currently in Use........................................................ 9 Lumping Techniques for Atmospheric Chemical Mechanisms ........................................ 12 Environmental Chamber Evaluations................................................................................ 15 Mechanism Intercomparisons ........................................................................................... 16 Variation in Model Predictions due to Photolysis Parameterizations and NMHC Reaction Mechanisms (Olson et al., 1997) .............................................. 16 Variations due to NMHC Chemistry (Kuhn et al., 1998) ..................................... 18 CURRENT STATUS FOR REACTIVITY MODELING............................................................ 19 CONCLUSIONS........................................................................................................................... 22 REFERENCES.............................................................................................................................. 24
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